Homogeneous Partial Oxidation of Methane to Methanol-a Simulation by CHEMKIN-III

oxidation

Abstract A simulation of homogeneous partial oxidation of methane to methanol by CHEMKIN-III Gas-Phase Mechanism Interpreter was carried out. The content of different species as functions of time and the effect of pressure, temperature and CH 4 /O 2 ratio were specially discussed HCHO was found the initial product, but it is easy to be oxidized to CO and its …

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On-line Solid-Phase Extraction of Arsanilic Acid from Water with Arsanilic Acid Imprinted Monolith

Abstract The synthesis and evaluation of a molecularly imprinting polymeric monolith (MIPM) as an on-line selective solid-phase extraction column, for the efficient preconcentration and determination of arsanilic acid (PABAA) in water was reported. MIPM was prepared by in situ polymerization using PABAA as the template molecule, methacrylic acid as the functional monomer and ethyleneglycol dimethacrylate as …

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Effects of cation-anion on recognition characteristics of sarafloxacin -Co(II) complex imprinted polymer in aqueous media

In this paper, a molecularly imprinted polymers (MIP) for sarafloxacin was prepared by the use of itaconic acid as the functional monomer and ethylene glycol dimethacrylate as the crosslinking monomer. To improve selectivity, cobalt(II) ions was used to form metal-template complex, which provided the specific binding sites similar to metal-chelate antibody. The influences of different …

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Preparation and characterization of high molecular weight poly(L-lactic acid) by chain extending

Abstract Poly(L-lactic acid) (PLLA) of high molecular weight was prepared by chain extending reaction in a micro-compounder. Phosphites were used as chain extenders to increase the molecular weight of the PLLA prepolymer that was prepared by bulk polycondensation of L-lactic acid. Effects of the amount of the phosphite, temperature and the screw speed were studied on …

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Synthesis and crystal structure of a novel Salen-copper(II) complex

Abstract The Salen-copper(II) complex was synthesized by diffusion. The structure was characterized by single crystal X-ray diffraction. It crystallized in triclinic system,pB1spacegroup, with a=9.3441(18)Å, b=11.478(3)Å, c=12.320(3)Å, a=81.584(11)°, b=74.681(9)°, g=68.206(9), MolecularFormula: C23H19CuN5O8, M=397.86, V=1181.6(5)Å3, z=2, Dc=1.56Mg/m3, R1=0.0416, wR2=0.1236,I>[2s/(I)]. The crystal included a mononuclear complex [Cu(H2L)(DMF)] and a non-coordinated H2O molecular. Keyword diaminomaleontrile;5-carboxylsalicylaldehyde;crystal structure Synthesis and Crystal Structure of a New Salen-Copper (II) Complex Li …

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Adsorption and competitive adsorption of heavy metal ions lead, cadmium and copper on d-manganese oxide

Abstracts d- MnO2 was prepared with hydrothermal treatment, and its crystalline structure was verified with X-ray diffraction spectroscopy. FTIR showed there were copious hydroxyl groups on the surface of d-MnO2 for the adsorption. The adsorption capacity of three kinds of heavy metal ions Pb2+, Cd2+ and Cu2+ on the d-MnO2 was all increased with the increase of ion concentration and the increase of …

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A new biflavonoid from Selaginella uncinata (Desv.) Spring

Abstract A new biflavonoid, 5,7,4′,5”-tetrahydroxy-7”-metroxy-[3-O-4”’] biflavone along with four known biflavonoids and one known phenolic acid was isolated from the herb of Selaginella uncinata(Desv.) Spring. Their structures were elucidated by spectroscopic methods. Keywords Selaginella uncinata;5,7,4′,5”-tetrahydroxy-7”-metroxy-[3-O-4”’] biflavone INTRODUCTION Selaginella uncinata(Desv.) Spring as a medicinal plant is used to treat acute infectious jaundice hepatitis, cholecystitis, enteritis and so on.In previous investigations of …

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Kinetic and thermodynamic studies on the adsorption of Ni 2+ onto chitosan-aluminium oxide composite material

Abstract Kinetics’ and Thermodynamics of The Adsorption of of Ni 2+ Onto Chitosan-Aluminum Composite Material’s WAS Studied oxide. The Under Experimental Conditions, s Indicated Kinetic Adsorption of that of Ni 2+ Onto Aluminum oxide-Chitosan Composite Material’s Conforms to pseudo-SECOND-Order Equation And the apparent adsorption activation energy is 28.62 kJ/mol.In the experimental temperature, thermodynamic studies indicated that adsorption of Ni 2+ onto chitosan-aluminium …

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Kinetics and mechanism of ruthenium(III) catalyzed oxidation of isobutyl alcohol by cerium(IV) in acid medium

Abstract The kinetics and mechanism of ruthenium(III) catalyzed oxidation of isobutyl alcohol(IBA) by cerium(IV) in sulfuric acid media has been investigated by titrimetric technique of redox in the temperature range of 298-313K. It is found that the reaction is first-order with respect to Ce(IV) and Ru(III), and a positive fractional order with respect to IBA. It …

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